Park, Jihye; Kim, Young Kwang; Kim, Guncheol published the artcile< Stereoselective formal synthesis of (-)-mesembrane via asymmetric allylation and resoluting condensation reactions>, Synthetic Route of 152140-65-3, the main research area is phenylcyclohexanone asym asym allylation; oxocyclohexaneacetamide intramol cyclocondensation resolution; mesembrane stereoselective formal synthesis.
A selective pathway to (-)-mesembrane by a combination of enantioselective allylation and intramol. amide-ketone cyclization was developed.
Bulletin of the Korean Chemical Society published new progress about Allylation, stereoselective. 152140-65-3 belongs to class chiral-phosphine-ligands, and the molecular formula is C54H42N2O2P2, Synthetic Route of 152140-65-3.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate