Park, Jihye; Kim, Young Kwang; Kim, Guncheol published the artcile< Stereoselective formal synthesis of (-)-mesembrane via asymmetric allylation and resoluting condensation reactions>, Safety of N,N’-(11R,12R)-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)benzamide], the main research area is phenylcyclohexanone asym asym allylation; oxocyclohexaneacetamide intramol cyclocondensation resolution; mesembrane stereoselective formal synthesis.
A selective pathway to (-)-mesembrane by a combination of enantioselective allylation and intramol. amide-ketone cyclization was developed.
Bulletin of the Korean Chemical Society published new progress about Allylation, stereoselective. 152140-65-3 belongs to class chiral-phosphine-ligands, and the molecular formula is C54H42N2O2P2, Safety of N,N’-(11R,12R)-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)benzamide].
Referemce:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate