The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium(SMILESS: CC1=C([P]2([Pd+2]3([CH2-]C4=C2C=CC=C4)[O-]/C(C)=O[Pd+2]5([O-]/C(C)=O3)[P](C6=C(C)C=CC=C6)(C7=C([CH2-]5)C=CC=C7)C8=C(C)C=CC=C8)C9=C(C)C=CC=C9)C=CC=C1,cas:172418-32-5) is researched.Recommanded Product: 1-(Bromomethyl)-2-iodobenzene. The article 《trans-Di(μ-acetato)bis[2-(di-2-tolylphosphino)benzyl]dipalladium(II)》 in relation to this compound, is published in Journal fuer Praktische Chemie (Weinheim, Germany). Let’s take a look at the latest research on this compound (cas:172418-32-5).
A brief review with 29 references is given on coupling reactions, including Suzuki and Heck reactions, with catalysis of the title complex (I). Exptl. data for the preparation of I and one example for the Heck reaction are provided.
This compound(trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium)Category: chiral-phosphine-ligands was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate