The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, is researched, Molecular C46H46O4P2Pd2, CAS is 172418-32-5, about Novel acyclic carbene-substituted phospha-palladacycles, the main research direction is acyclic palladium carbene phospha palladacycle substituted preparation; dialkyl aminocarbene reaction phospha palladacycle.COA of Formula: C46H46O4P2Pd2.
The synthesis of the first phospha-palladacycle substituted with an acyclic carbene is reported. The reaction of bis(dialkyl)aminocarbenes with the very stable phospha-palladacycles leads to metastable η1-carbene complexes, which can be converted by intramol. reduction to zero valent palladium complexes.
《Novel acyclic carbene-substituted phospha-palladacycles》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium)COA of Formula: C46H46O4P2Pd2.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate