Chavez, Patricia; Bulut, Ibrahim; Fall, Sadiara; Ibraikulov, Olzhas A.; Chochos, Christos L.; Bartringer, Jeremy; Heiser, Thomas; Leveque, Patrick; Leclerc, Nicolas published the article 《An electron-transporting thiazole-based polymer synthesized through direct (hetero)arylation polymerization》. Keywords: direct hetero arylation polymerization electron transporting thiazole polymer; direct (hetero)arylation polycondensation; n-type polymer; organic solar cell; thiazole-based DPP.They researched the compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium( cas:172418-32-5 ).Product Details of 172418-32-5. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:172418-32-5) here.
In this work, a new n-type polymer based on a thiazole-diketopyrrolopyrrole unit has been synthesized through direct (hetero)arylation polycondensation. The molar mass has been optimized by systematic variation of the the monomer concentration Optical and electrochem. properties have been studied. They clearly suggested that this polymer possess a high electron affinity together with a very interesting absorption band, making it a good non-fullerene acceptor candidate. As a consequence, its charge transport and photovoltaic properties in a blend with the usual P3HT electron-donating polymer have been investigated.
《An electron-transporting thiazole-based polymer synthesized through direct (hetero)arylation polymerization》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium)Product Details of 172418-32-5.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate