Computed Properties of C46H46O4P2Pd2. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, is researched, Molecular C46H46O4P2Pd2, CAS is 172418-32-5, about A route to Pd0 from PdII metallacycles in amination and cross-coupling chemistry. Author is Louie, Janis; Hartwig, John F..
Catalytically active Pd0 complexes can be formed from complex I (R = o-tolyl throughout this abstract) by 2 different routes: β-hydrogen elimination of a Pd amide or C-C bond-forming reductive elimination involving a Pd Ph substituent. It was difficult to determined conclusively if these reactions occur in the catalytic chem. of I. However, they provide I with an entry into catalysis by Pd0/PdII pathways which should be included in mechanistic considerations. The crystal structure of II formed by cleavage of I with Et2NH was determined
《A route to Pd0 from PdII metallacycles in amination and cross-coupling chemistry》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium)Computed Properties of C46H46O4P2Pd2.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate