COA of Formula: C54H45ClP3Rh. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Tris(triphenylphosphine)chlororhodium, is researched, Molecular C54H45ClP3Rh, CAS is 14694-95-2, about The Fischer-Tropsch reaction in the aqueous phase over rhodium catalysts: a promising route to selective synthesis and separation of oxygenates and hydrocarbons. Author is Peregudova, Aleksandra S.; Barrios, Alan J.; Ordomsky, Vitaly V.; Borisova, Nataliya E.; Khodakov, Andrei Y..
We uncovered the aqueous phase Fischer-Tropsch reaction over Rh catalysts. The reaction results in the synthesis and consecutive separation of hydrocarbons and oxygenates into 2 phases. Use of a Rh Schiff base complex as a precursor for catalyst preparation allows efficient control of the Rh metal nanoparticle size distribution and leads to higher alc. selectivity.
This compound(Tris(triphenylphosphine)chlororhodium)COA of Formula: C54H45ClP3Rh was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate