Quality Control of trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, is researched, Molecular C46H46O4P2Pd2, CAS is 172418-32-5, about Facile generation and morphology of Pd nanoparticles from palladacycles and carbon monoxide. Author is Grigg, Ronald; Zhang, Lixin; Collard, Simon; Ellis, Peter; Keep, Ann.
Treatment of PdCys or Pd salts with CO (1 atm) in DMF or toluene at room temperature results in a solution of Pd nanoparticles whose morphol. depends on the PdCy or Pd salt. Unusual triangular shaped 2-12 nm nanoparticles result from some PdCys. Crystals of a compound formed by insertion of CO into palladacycle ligands are monoclinic, space group P21/n, with a 12.3417(3), b 10.9267(3), c 15.8504(6) Å; Z = 2; R = 0.049, wR2 = 0.1118.
The article 《Facile generation and morphology of Pd nanoparticles from palladacycles and carbon monoxide》 also mentions many details about this compound(172418-32-5)Quality Control of trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, you can pay attention to it, because details determine success or failure
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate