Product Details of 40400-13-3. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 1-(Bromomethyl)-2-iodobenzene, is researched, Molecular C7H6BrI, CAS is 40400-13-3, about A Synthetic Route to Benzothiazocines with Two or Three Carbon Stereocenters via Copper-Catalyzed Intramolecular N-Arylation.
A new structural family of benzothiazocines, e.g. I, bearing two or three carbon stereogenic centers on the 8-membered ring was synthesized by intramol. Cu-catalyzed N-arylation. The chiral racemic 1,3-aminothioethers precursors have been prepared from easily available starting materials. An ionic organic base was used for the first time in an intramol. C-N coupling, in medium-ring series, leading to higher yields than those obtained with an inorganic base, and a partial epimerization in some cases. The synthetic sequence was successfully performed on one example in asym. version, demonstrating the accessibility of enantioenriched benzothiazocines.
Different reactions of this compound(1-(Bromomethyl)-2-iodobenzene)Product Details of 40400-13-3 require different conditions, so the reaction conditions are very important.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate