Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 40400-13-3, is researched, SMILESS is BrCC1=C(I)C=CC=C1, Molecular C7H6BrIJournal, Article, Chemical Communications (Cambridge, United Kingdom) called Frustrated Lewis pair catalyzed hydrodehalogenation of benzyl-halides, Author is Wang, Tongtong; Xu, Maotong; Jupp, Andrew R.; Chen, Shi-Ming; Qu, Zheng-Wang; Grimme, Stefan; Stephan, Douglas W., the main research direction is toluene preparation; benzyl halide hydrodehalogenation frustrated Lewis pair catalyst.Computed Properties of C7H6BrI.
10 Mol% B(2,6-C6F2H3)3 in the presence of excess tetramethylpiperidine (TMP) and H2 (or D2) is shown to catalyze the hydrogenative dehalogenation of benzyl-halides to give corresponding toluene derivatives These reactions proceed via an initial FLP activation of H2 yielding the ammonium hydridoborate [TMPH][HB(2,6-C6F2H3)3]. This species acts in analogy to a FLP to cooperatively activate C-X bond (X = Cl, Br, I) of benzyl-halides delivering hydride and generating the corresponding ammonium halide salts.
Different reactions of this compound(1-(Bromomethyl)-2-iodobenzene)Computed Properties of C7H6BrI require different conditions, so the reaction conditions are very important.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate