Quality Control of trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, is researched, Molecular C46H46O4P2Pd2, CAS is 172418-32-5, about High yield [125I]iodide-labeling of iodinated carboranes by palladium-catalyzed isotopic exchange. Author is Winberg, Karl Johan; Barbera, Gemma; Eriksson, Ludvig; Teixidor, Francesc; Tolmachev, Vladimir; Vinas, Clara; Sjoberg, Stefan.
The authors have recently shown the feasibility of Pd-catalyzed isotopic exchange between [125I]iodide and 2-iodo-para-carborane. The authors have modified the methodol. and extended its application to a wider range of iodinated carboranes. Thus, by using Herrmann’s catalyst in toluene at 100°, 2-I-p-, 3-I-o-, 9-I-o-, 9-I-m-carborane, 1-phenyl-3-I-o-carborane and 1,2-diphenyl-3-I-o-carborane were radiolabeled with 125iodine in high to excellent yields.
The article 《High yield [125I]iodide-labeling of iodinated carboranes by palladium-catalyzed isotopic exchange》 also mentions many details about this compound(172418-32-5)Quality Control of trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, you can pay attention to it, because details determine success or failure
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate