Quality Control of 1-(Bromomethyl)-2-iodobenzene. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 1-(Bromomethyl)-2-iodobenzene, is researched, Molecular C7H6BrI, CAS is 40400-13-3, about Functionalization of 1,3,4-Oxadiazoles and 1,2,4-Triazoles via Selective Zincation or Magnesiation Using 2,2,6,6-Tetramethylpiperidyl Bases. Author is Schwaerzer, Kuno; Tuellmann, Carl Phillip; Grassl, Simon; Gorski, Bartosz; Brocklehurst, Cara E.; Knochel, Paul.
The metalation of the 1,3,4-oxadiazole and 1,2,4-triazole scaffolds via regioselective zincation or magnesiation using the TMP bases (TMP = 2,2,6,6-tetramethylpiperidyl) TMP2Zn.2LiCl, TMP2Zn.2MgCl2.2LiCl, TMPMgCl.LiCl, and TMPZnCl.LiCl under mild conditions in THF is reported. Subsequent trapping with various electrophiles including hydroxylamino benzoates gives access to functionalized heterocycles while tolerating many functional groups.
The article 《Functionalization of 1,3,4-Oxadiazoles and 1,2,4-Triazoles via Selective Zincation or Magnesiation Using 2,2,6,6-Tetramethylpiperidyl Bases》 also mentions many details about this compound(40400-13-3)Quality Control of 1-(Bromomethyl)-2-iodobenzene, you can pay attention to it, because details determine success or failure
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate