The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 1-(Bromomethyl)-2-iodobenzene(SMILESS: BrCC1=C(I)C=CC=C1,cas:40400-13-3) is researched.Recommanded Product: 40400-13-3. The article 《Oxidative cross-dehydrogenative coupling between iodoarenes and acylanilides for C-N bond formation under metal-free conditions》 in relation to this compound, is published in Organic Chemistry Frontiers. Let’s take a look at the latest research on this compound (cas:40400-13-3).
A novel metal-free C-N bond formation method through oxidative cross-dehydrogenative coupling between iodoarenes RI (R = Ph, 3-methylphenyl, 3,5-dimethylphenyl, etc.) and acylanilides R1NHC(O)R2 (R1 = Ph, 3-chloro-4-methylphenyl, 2-bromophenyl, etc.; R2 = Me, Ph, cyclopropyl, etc.) was developed. The reaction was mediated by mCPBA without any metal catalysts or additives. The reaction exhibited high para-selectivity with the retention of an iodine atom which enabled further transformations. This method also possessed the merits of substrate availability, easy operation and atom economy. It provides a simple and efficient route for the preparation of functionalized N-aryl amides I (R = H, 3-Me, 3,5-di-Me, 2,6-di-Me, etc.).
Although many compounds look similar to this compound(40400-13-3)Reference of 1-(Bromomethyl)-2-iodobenzene, numerous studies have shown that this compound(SMILES:BrCC1=C(I)C=CC=C1), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate