Application In Synthesis of Tris(triphenylphosphine)chlororhodium. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Tris(triphenylphosphine)chlororhodium, is researched, Molecular C54H45ClP3Rh, CAS is 14694-95-2, about Stereoselective β-Mannosylation via Anomeric O-Alkylation with L-Sugar-Derived Electrophiles. Author is Hettiarachchi, Ishani Lakshika; Meng, Shuai; Chahine, Mira; Li, Xiaohua; Zhu, Jianglong.
A total synthesis of the trisaccharide repeat unit of Salmonella serogroup E1 O-antigen is reported. This synthesis features a key β-mannosylation reaction through a cesium carbonate-mediated anomeric O-alkylation of a partially protected D-mannose with an L-fucose-derived electrophile for the first time.
After consulting a lot of data, we found that this compound(14694-95-2)Application In Synthesis of Tris(triphenylphosphine)chlororhodium can be used in many types of reactions. And in most cases, this compound has more advantages.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate