Downstream Synthetic Route Of 14694-95-2

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The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Towards Visible-Light Photocatalytic Reduction of Hypercoordinated Silicon Species》. Authors are Levernier, Etienne; Leveque, Christophe; Derat, Etienne; Fensterbank, Louis; Ollivier, Cyril.The article about the compound:Tris(triphenylphosphine)chlororhodiumcas:14694-95-2,SMILESS:[Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9).Quality Control of Tris(triphenylphosphine)chlororhodium. Through the article, more information about this compound (cas:14694-95-2) is conveyed.

Nowadays, the quest of new radical precursors based on heteroatom complexes occupies an increasingly prominent position in contemporary research. Herein, the authors studied the behavior and the limitations of hexa- or pentacoordinated organochlorosilanes and related pentacoordinated silyliums as new families of complexes for the generation of radicals under photocatalytic reductive conditions. Particularly, treatment of chloro(phenyl)bis[N,S-pyridine-2-thiolato(-)]silicon(IV) or the related silylium derivative with the fac-Ir(ppy)3 (5 mol-%)/NEt3 (1.5 equiv) system under blue LEDs irradiation generates a thiopyridyl radical which can participate in the formation of a C-S bond by reaction with an allylsulfone. Computational studies supported this exptl. finding, and particularly by showing that homolytic fragmentation of C-Ts bond is favored over the fragmentation of thiopyridyl radical.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate