Synthetic Route of C7H6BrI. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 1-(Bromomethyl)-2-iodobenzene, is researched, Molecular C7H6BrI, CAS is 40400-13-3, about Intramolecular Homolytic Substitution Enabled by Photoredox Catalysis: Sulfur, Phosphorus, and Silicon Heterocycle Synthesis from Aryl Halides. Author is Garrido-Castro, Alberto F.; Salaverri, Noelia; Maestro, M. Carmen; Aleman, Jose.
Aryl radical generation and manipulation constitutes a long-standing challenge in organic synthesis. Photocatalytic single-electron reduction of aryl halides was established as a premier activation pathway to reach these intermediates. The current study integrates the conceptual simplicity of the classical intramol. homolytic substitution with the practicality of the modern photocatalytic approach. Predicated on an efficient metal-free dehalogenation of aryl halides under mild organo-photoredox conditions, sulfur, phosphorus, and silicon heteroatoms capture the C(sp2)-centered radical in an intramol. fashion.
This literature about this compound(40400-13-3)Synthetic Route of C7H6BrIhas given us a lot of inspiration, and I hope that the research on this compound(1-(Bromomethyl)-2-iodobenzene) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate