Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, New Journal of Chemistry called A facile approach for the synthesis of novel silsesquioxanes with mixed functional groups, Author is Walczak, Marcin; Januszewski, Rafal; Dutkiewicz, Michal; Franczyk, Adrian; Marciniec, Bogdan, which mentions a compound: 14694-95-2, SMILESS is [Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9, Molecular C54H45ClP3Rh, Computed Properties of C54H45ClP3Rh.
An efficient method for the preparation of new silsesquioxanes with mixed functional groups (RSiMe2O)n(ViSiMe2O)8-nSi8O12 is described. The proposed protocols are based on hydrosilylation of octakis(dimethylvinylsiloxy)octasilsesquioxane ((ViSiMe2O)8Si8O12) with unsym. disiloxanes. As an example of possible modification of (RSiMe2O)n(ViSiMe2O)8-nSi8O12 derivatives, a thiol addition was distinguished. Silsesquioxane compounds with a variety of functional groups (silylamine, epoxy, and Cl) were obtained and characterized. The obtained compounds can be considered as novel multi-substituted materials, which significantly increase the possibility of the synthesis and design of new functional materials.
This literature about this compound(14694-95-2)Computed Properties of C54H45ClP3Rhhas given us a lot of inspiration, and I hope that the research on this compound(Tris(triphenylphosphine)chlororhodium) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate