The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium(SMILESS: CC1=C([P]2([Pd+2]3([CH2-]C4=C2C=CC=C4)[O-]/C(C)=O[Pd+2]5([O-]/C(C)=O3)[P](C6=C(C)C=CC=C6)(C7=C([CH2-]5)C=CC=C7)C8=C(C)C=CC=C8)C9=C(C)C=CC=C9)C=CC=C1,cas:172418-32-5) is researched.Electric Literature of C7H14O6. The article 《A novel palladium-catalyzed cyclization of β-iodo-β,γ-enones toward 2,5-disubstituted-furans》 in relation to this compound, is published in Tetrahedron Letters. Let’s take a look at the latest research on this compound (cas:172418-32-5).
The use of palladacycle catalyst I (R = o-tolyl) to the transformation of (Z)-β-iodo-β,γ-enones Me(CH2)4CH:CICH2COR (R = Ph, 2-furyl, 2-thienyl, Me, pentyl) into the corresponding 2,5-disubstituted furans II in good yields at room temperature was described. The comparison of using other kinds of palladium catalysts under the similar reaction conditions was also described.
Compounds in my other articles are similar to this one(trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium)HPLC of Formula: 172418-32-5, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate