Synthetic Route of C46H46O4P2Pd2. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, is researched, Molecular C46H46O4P2Pd2, CAS is 172418-32-5, about Anion-Accelerated Palladium-Catalyzed Intramolecular Coupling of Phenols with Aryl Halides.
A new procedure is described for the intramol. coupling of phenols with aryl halides. The coupling is promoted by a novel palladacyclic catalyst, formed from Pd(OAc)2 and P(o-tolyl)3, and is significantly accelerated using bases. E.g., Pd(OAc)2/P(o-tolyl)3 catalyzed the intramol. coupling of 3-HOC6H4OCH2C6H4I-2 in the presence of Cs2CO3 to give 94% I.
In some applications, this compound(172418-32-5)Synthetic Route of C46H46O4P2Pd2 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate