Simple exploration of 14694-95-2

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Related Products of 14694-95-2. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Tris(triphenylphosphine)chlororhodium, is researched, Molecular C54H45ClP3Rh, CAS is 14694-95-2, about Bis(6-diphenylphosphino-acenaphth-5-yl)sulfoxide: A New Ligand for Late Transition Metal Complexes. Author is Meyer, Fabio; Hupf, Emanuel; Lork, Enno; Grabowsky, Simon; Mebs, Stefan; Beckmann, Jens.

The synthesis of the new ligand bis(6-diphenylphosphinoacenaphth-5-yl)sulfoxide, [6-(Ph2P)-5-Ace-6]2-SO (1), is presented along with six transition metal complexes thereof, namely, 1·MCl (M = Rh, Cu, Ag, Au) and 1·MCl2 (M = Ni, Pd). Within these novel complexes, close metal-sulfur distances are observed and the nature of the M-S coordination, as well as the response of the +S-O- bond, are investigated in detail with a set of spectroscopic, crystallog. and real-space bonding indicators.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate