Recommanded Product: 1-(Bromomethyl)-2-iodobenzene. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: 1-(Bromomethyl)-2-iodobenzene, is researched, Molecular C7H6BrI, CAS is 40400-13-3, about Nickel-Catalyzed Asymmetric Intramolecular Reductive Heck Reaction of Unactivated Alkenes. Author is Yang, Feiyan; Jin, Youxiang; Wang, Chuan.
In the presence of Ni(BF4)2 and a nonracemic pyridinyloxazoline and with Zn as reductant and i-PrOH as solvent, alkenyl-substituted aryl bromides such as I underwent enantioselective reductive Heck reactions to yield nonracemic indanes, benzofurans, and indolines such as II with quaternary stereocenters. A mechanism is proposed involving enantiodetermining migratory insertion followed by protonation with water or an alc. solvent.
There are many compounds similar to this compound(40400-13-3)Recommanded Product: 1-(Bromomethyl)-2-iodobenzene. if you want to know more, you can check out my other articles. I hope it will help you，maybe you’ll find some useful information.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate