Product Details of 172418-32-5. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, is researched, Molecular C46H46O4P2Pd2, CAS is 172418-32-5, about An alternative approach to 3-(diphenylphosphino)hexahelicene. Author is Aloui, Faouzi; Ben Hassine, Bechir.
3-(Diphenylphosphino)hexahelicene is synthesized in good yield and purity, via a three-step sequence involving a palladium-catalyzed Mizoroki-Heck coupling reaction and classical oxidative photocyclisation. Mononuclear ruthenium and palladium complexes of 3-(diphenylphosphino)hexahelicene are prepared and characterized.
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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate