Chai, Hongxin; Cao, Qun; Dornan, Laura M.; Hughes, N. Louise; Brown, Clare L.; Nockemann, Peter; Li, Jiarong; Muldoon, Mark J. published the article 《Cationic Palladium(II) Complexes for Catalytic Wacker-Type Oxidation of Styrenes to Ketones Using O2 as the Sole Oxidant》. Keywords: styrene palladium complex oxygen Wacker oxidation catalyst; ketone preparation.They researched the compound: 5-Chloropicolinaldehyde( cas:31181-89-2 ).SDS of cas: 31181-89-2. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:31181-89-2) here.
A series of new cationic palladium(II) complexes were prepared and studied for their ability to catalyze the Wacker-type oxidation of styrenes to their corresponding acetophenones using O2 as the sole oxidant. Catalysts are active at room temperature and the study highlights the importance of solvent choice and the need for ligand development in improving catalyst performance.
Here is just a brief introduction to this compound(31181-89-2)SDS of cas: 31181-89-2, more information about the compound(5-Chloropicolinaldehyde) is in the article, you can click the link below.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate