Fun Route: New Discovery of 172418-32-5

I hope my short article helps more people learn about this compound(trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium)Reference of trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium. Apart from the compound(172418-32-5), you can read my other articles to know other related compounds.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Rapid Palladium-Catalyzed Synthesis of Esters from Aryl Halides Utilizing Mo(CO)6 as a Solid Carbon Monoxide Source, published in 2003-08-31, which mentions a compound: 172418-32-5, Name is trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, Molecular C46H46O4P2Pd2, Reference of trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium.

A series of aromatic esters R1CO2R2 (R1 = 3-BrC6H4, 2-MeC6H4, 4-MeOC6H4, 4-F3CC6H4, 1-naphthyl; R2 = Bu, Me3SiCH2CH2, PhCH2) was synthesized in moderate to high yields (52-89%) via palladium-catalyzed carbonylation of aryl halides R1X (X = Br, iodo) in the presence of excess of a primary alc. R2OH under microwave irradiation using Mo(CO)6 as a solid carbon monoxide source. The reactions with sterically hindered tert-butanol as an alc. failed or gave low yields of the desired products.

I hope my short article helps more people learn about this compound(trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium)Reference of trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium. Apart from the compound(172418-32-5), you can read my other articles to know other related compounds.

Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate