Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 1824-94-8, is researched, Molecular C7H14O6, about TBAF Effects 3,6-Anhydro Formation from 6-O-Tosyl Pyranosides, the main research direction is crystal structure glycoside preparation; aminoglycoside glycoside preparation anhydro sugar furanodictine sauropunol anhydrofuranoside furanodictine.Recommanded Product: (2R,3R,4S,5R,6R)-2-(Hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol.
3,6-Anhydro sugars are common structures in algal polysaccharides and occur in the furanodictine and sauropunol natural products. We have found that treatment of 6-O-tosylpyranosides with tetrabutylammonium fluoride provides a mild, high-yielding synthesis of 3,6-anhydro sugars. Using O-glycoside substrates, 3,6-anhydropyranosides are isolated and the use of N,O-di-Me hydroxylamine glycosides yields 3,6-anhydrofuranosides. Applying this approach, concise synthetic routes to several 3,6-anhydro sugar natural products, e.g. I, are reported, including furanodictine A and sauropunols A-D.
From this literature《TBAF Effects 3,6-Anhydro Formation from 6-O-Tosyl Pyranosides》,we know some information about this compound(1824-94-8)Recommanded Product: (2R,3R,4S,5R,6R)-2-(Hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol, but this is not all information, there are many literatures related to this compound(1824-94-8).
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate