Computed Properties of C7H6BrI. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 1-(Bromomethyl)-2-iodobenzene, is researched, Molecular C7H6BrI, CAS is 40400-13-3, about Phenalenannulations: Three-Point Double Annulation Reactions that Convert Benzenes into Pyrenes. Author is Kawade, Rahul Kisan; Hu, Chaowei; Dos Santos, Nikolas R.; Watson, Noelle; Lin, Xinsong; Hanson, Kenneth; Alabugin, Igor V..
3-Point annulations, or phenalenannulations, transform a benzene ring directly into a substituted pyrene by “”wrapping”” two new cycles around the perimeter of the central ring at three consecutive carbon atoms. This efficient, modular, and general method for π-extension opens access to non-sym. pyrenes and their expanded analogs, e.g., I. Potentially, this approach can convert any aromatic ring bearing a -CH2Br or a -CHO group into a pyrene moiety. Depending upon the workup choices, the process can be directed towards either tin- or iodo-substituted product formation, giving complementary choices for further various cross-coupling reactions. The two-directional bis-double annulation adds two new polyaromatic extensions with a total of six new aromatic rings at a central core.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate