Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 1824-94-8, is researched, SMILESS is O[C@H]([C@H]([C@H]([C@@H](CO)O1)O)O)[C@@H]1OC, Molecular C7H14O6Journal, European Journal of Organic Chemistry called Purine Unit as a Building Block of Artificial Receptors Designed for the Recognition of Carbohydrates, Author is Kaiser, Stefan; Geffert, Christoph; Mazik, Monika, the main research direction is purine artificial receptor mol recognition carbohydrate.Formula: C7H14O6.
1,3,5-Substituted 2,4,6-triethylbenzene derivatives bearing pyridine/pyrimidine and purine units were synthesized and their potential to function as carbohydrate receptors was evaluated. Compounds consisting of 2-chloro-9H(7H)-purin-6-yl unit (e.g., I) have the ability to act both as carbohydrate-binding agents and as a basis for further functionalization through the nucleophilic displacement of the chlorine atom. Microwave-assisted reactions and/or the application of sealed tubes allowed the preparation of derivatives with a varying substituent pattern on the purine ring. The relatively drastic reaction conditions required for the successful functionalization reflect the unfavorable influence of the bulky C6-substituent on the nucleophilic substitution at purine C2. Initial binding studies towards carbohydrates showed that the properties of this type of purine-bearing compounds can be fine-tuned by the variation of the C2-substituent of the purine ring and represents a valuable basis for the identification of new structure-activity relationships. Such findings are of high importance for further developments in the area of mol. recognition of carbohydrates by artificial receptors.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate