Extended knowledge of 14694-95-2

There is still a lot of research devoted to this compound(SMILES：[Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)Safety of Tris(triphenylphosphine)chlororhodium, and with the development of science, more effects of this compound(14694-95-2) can be discovered.

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Bartlewicz, Olga; Zielinski, Michal; Kaczmarek, Marta; Maciejewski, Hieronim researched the compound: Tris(triphenylphosphine)chlororhodium( cas:14694-95-2 ).Safety of Tris(triphenylphosphine)chlororhodium.They published the article 《Synthesis, characterization and catalytic activity of new SILPs based on MgO-SiO2 and MgO-SiO2/lignin supports》 about this compound( cas:14694-95-2 ) in Molecular Catalysis. Keywords: magnesium oxide silica ionic liquid hydrosilylation catalyst. We’ll tell you more about this compound (cas:14694-95-2).

New Supported Ionic Liquid Phase (SILP) materials on magnesium oxide-silica (MgO-SiO2) and magnesium oxide-silica/lignin (MgO-SiO2/lignin) supports were obtained. The new SILP materials contain imidazolium, pyridinium, phosphonium and sulfonium cations and methylsulfate as well as bis(trifluoromethylsulfonyl)imide anions. The obtained systems were subjected to detailed physicochem. characterization by: XRD, SEM-EDX, elemental anal., thermogravimetric measurements, IR spectroscopy and particle size determination The adsorption properties of both, the supports and the obtained SILP materials, were addnl. determined The catalytic activity and possibility of reusing the obtained SILP systems were confirmed in the hydrosilylation reaction of 1-octene with 1,1,1,3,5,5,5-heptamethyltrisiloxane.

There is still a lot of research devoted to this compound(SMILES：[Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)Safety of Tris(triphenylphosphine)chlororhodium, and with the development of science, more effects of this compound(14694-95-2) can be discovered.

Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate