So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Mo, Dong-Liang; Yuan, Teng; Ding, Chang-Hua; Dai, Li-Xin; Hou, Xue-Long researched the compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium( cas:172418-32-5 ).Quality Control of trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium.They published the article 《Palladacycle-Catalyzed Methylenecyclopropanation of Bicyclic Alkenes with Propiolates》 about this compound( cas:172418-32-5 ) in Journal of Organic Chemistry. Keywords: palladacycle catalyzed methylenecyclopropanation bicyclic alkene propiolate crystallog. We’ll tell you more about this compound (cas:172418-32-5).
An efficient way to access functionalized methylenecyclopropanes was developed by palladacycle-catalyzed cyclopropanation of bicyclic alkenes with propiolates in high yields. The structure of the palladacycle was kept intact in the reaction, shown by 31P NMR spectrum studies. A rational mechanism was proposed with a deuterium-labeled experiment The usefulness of the functionalized methylenecyclopropanes also was demonstrated.
From this literature《Palladacycle-Catalyzed Methylenecyclopropanation of Bicyclic Alkenes with Propiolates》,we know some information about this compound(172418-32-5)Quality Control of trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, but this is not all information, there are many literatures related to this compound(172418-32-5).
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate