Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 172418-32-5, is researched, SMILESS is CC1=C([P]2([Pd+2]3([CH2-]C4=C2C=CC=C4)[O-]/C(C)=O[Pd+2]5([O-]/C(C)=O3)[P](C6=C(C)C=CC=C6)(C7=C([CH2-]5)C=CC=C7)C8=C(C)C=CC=C8)C9=C(C)C=CC=C9)C=CC=C1, Molecular C46H46O4P2Pd2Journal, Journal of Chemical Education called Introduction to homogeneous catalysis: carbon-carbon bond formation catalyzed by a defined palladium complex, Author is Herrmann, Wolfgang A.; Bohm, Volker P. W.; Reisinger, Claus-Peter, the main research direction is homogeneous catalysis carbon bond formation palladium complex; phosphine palladium complex catalysis carbon bond preparation.SDS of cas: 172418-32-5.
Carbon-carbon bond-forming reactions are key steps in many syntheses of organic chems. and natural products. A 4-day exptl. series offered to advanced fourth-year undergraduate students who are interested in organometallic chem. is presented. These experiments introduce students to the preparation of air-sensitive and oxygen-sensitive (phosphine ligand) compounds, concepts of organometallic chem. (ligand exchange, cyclometallation, oxidative addition, transmetalation, olefin insertion, reductive elimination and β-hydride-elimination), and practical catalysis by carrying out 2 important carbon-carbon bond-forming reactions.
There is still a lot of research devoted to this compound(SMILES：CC1=C([P]2([Pd+2]3([CH2-]C4=C2C=CC=C4)[O-]/C(C)=O[Pd+2]5([O-]/C(C)=O3)[P](C6=C(C)C=CC=C6)(C7=C([CH2-]5)C=CC=C7)C8=C(C)C=CC=C8)C9=C(C)C=CC=C9)C=CC=C1)SDS of cas: 172418-32-5, and with the development of science, more effects of this compound(172418-32-5) can be discovered.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate