Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 14694-95-2, is researched, SMILESS is [Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9, Molecular C54H45ClP3RhJournal, Polyhedron called Synthesis of a rhodium(III) triphenylphosphine complex via C-S bond cleavage of an azo-thioether ligand: X-ray structure, electrochemistry and catalysis towards transfer hydrogenation of ketones, Author is Roy, Puspendu; Manna, Chandan Kumar; Naskar, Rahul; Mondal, Tapan Kumar, the main research direction is rhodium triphenylphosphine thiophenylazenyl complex preparation crystal mol structure electrochem; catalysis transfer hydrogenation ketone rhodium triphenylphosphine thiophenylazenyl complex.Name: Tris(triphenylphosphine)chlororhodium.
A new rhodium(III) triphenylphosphine complex having the general formula [Rh(PPh3)2(L)Cl] (1) was synthesized by C-S bond cleavage of an ONS donor azo-thioether ligand (L-CH2Ph). The complex was thoroughly characterized by various spectroscopic techniques. Its single crystal x-ray structure exhibits an octahedral geometry around the rhodium(III) center. A cyclic voltammogram of the complex exhibits ligand based quasi-irreversible oxidative and reductive responses. The electronic structure, redox properties and electronic excitations in the complex were interpreted by DFT and TDDFT calculations The complex effectively catalyzed the transfer hydrogenation reaction of ketones with high yields in i-PrOH in the presence of a base.
There is still a lot of research devoted to this compound(SMILES：[Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)Name: Tris(triphenylphosphine)chlororhodium, and with the development of science, more effects of this compound(14694-95-2) can be discovered.
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate