Recommanded Product: 172418-32-5. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium, is researched, Molecular C46H46O4P2Pd2, CAS is 172418-32-5, about Efficient Synthesis of an Enantiopure Thiasteroid by a Double Heck Reaction. Author is Tietze, Lutz F.; Luecke, Lars P.; Major, Felix; Mueller, Peter.
The thiaestrane, I, was synthesized by two sequential Heck reactions starting from the thiophene derivatives which contain a (Z)-halogenovinyl group, and the enantiopure hydrindene II. The first intermol. Pd-catalyzed reaction leads to III (X = Br, I) in a highly regio- and diastereoselective manner. A subsequent intramol. Heck reaction catalyzed by a palladacycle then gave the thiasteroid I with an unusual cis-junction of the rings B and C.
If you want to learn more about this compound(trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium)Recommanded Product: 172418-32-5, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(172418-32-5).
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate