Chemistry Milestones Of 14694-95-2

There is still a lot of research devoted to this compound(SMILES：[Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)COA of Formula: C54H45ClP3Rh, and with the development of science, more effects of this compound(14694-95-2) can be discovered.

COA of Formula: C54H45ClP3Rh. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Tris(triphenylphosphine)chlororhodium, is researched, Molecular C54H45ClP3Rh, CAS is 14694-95-2, about Polyethylene Containing Triblock Copolymers Synthesized by Post-polymerization Functionalization. Author is Yan, Tianwei; Guironnet, Damien.

We report the synthesis of amphiphilic triblock copolymers containing a polyethylene block as the center block. The synthetic methodol. consists of performing four consecutive post-polymerization reactions on polyethylene to yield a dihydroxyl-terminated polymer. First, a cross-metathesis reaction converts the olefinic end-group of the polyethylene into an α,β-unsaturated ester followed by isomerization of the double bond and then its hydroformylation. This sequence introduces an aldehyde group randomly distributed along the polymer backbone. Finally, the reduction of the aldehyde- and ester-functionalized polymer yields two terminal hydroxyl groups. The methodol. was first established using low-mol.-weight model substrates before being performed on a polyethylene with a mol. weight of Mn = 13 kg mol-1. The functionalized polyethylene was used to initiate the ring-opening polymerizations of ε-caprolactone and tert-Bu glycidyl ether to yield the corresponding triblock copolymers. Subsequent hydrolysis of the tert-Bu groups in the polyether yielded an amphiphilic polymer that formed micelles in water.

There is still a lot of research devoted to this compound(SMILES：[Rh]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6.P(C7=CC=CC=C7)(C8=CC=CC=C8)C9=CC=CC=C9)COA of Formula: C54H45ClP3Rh, and with the development of science, more effects of this compound(14694-95-2) can be discovered.

Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate