Sep-21 News Extended knowledge of 1,1-Bis(diphenylphosphino)ferrocene

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, molecular formula is C34H28FeP2. In a Article,once mentioned of 12150-46-8, Recommanded Product: 12150-46-8

Reactions of 1,1′-bis(diphenylphosphino)ferrocene (BPPF) with Fe2(CO)9 and Fe3(CO)12 produced a series of iron carbonyl derivatives: (eta2-BPPF)Fe(CO)3 (1). (eta1-BPFF)Fe(CO)4 (2), (mu,eta2-BPFF)(Fe(CO)4)2 (3), (eta2-BPPF)Fe2(CO)7 (4), and (mu,eta2-BPPF)Fe3(CO)10 (5).The synthesis and characterization of 4 and 5, including X-ray crystal structures of 2, 3, and 5, confirmed various coordination modes of BPPF.Crystal data are as follows: (eta1-BPPF)Fe(CO)4 (2): orthorhombic, space group Pbca, a = 26.27(1), b = 23.18(1), c = 10.938(8) Angstroem, V = 6661(7) Angstroem3, Z = 8; 3017 data with I above 3.0?(I) were refined to R = 0.057, Rw = 0.056; (mu,eta2-BPPF)Fe3(CO)10 (5): monoclinic, space group P21/n, a = 11.231(1), b = 21.043(4), c = 20.373(9) Angstroem, beta = 97.373(9) deg, V = 4693(4) Angstroem3, Z = 4; 6082 data with I above 3.0?(I) were refined to R = 0.054, Rw = 0.071; (mu,eta2-BPPF)Fe2(CO)8 (3); monoclinic, space group C21/c, a = 17.223(7), b = 14.97(2), c = 18.558(3) Angstroem, beta = 108.39(3) deg, V = 4541(6) Angstroem3, Z = 4; 3201 data with I above 3.0?(I) were refined to R = 0.070, Rw =0.139, as a result of difficulties with modeling electron density peaks associated with highly disordered solvent atoms.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate