Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, category: chiral-phosphine-ligands.
Treatment of diphosphines Ph2P(CH2) nPPh2 (n = 1, 2, 4, 6) and [Fe(eta5-C 5H4PR?2)2] (R? = Ph, iPr) with a two-fold excess of (RO)2P(S)N3 (R = Et, Ph) results in the high-yield formation of the N-thiophosphorylated bis(iminophosphorane) derivatives (CH2)n[P{NP(S)(OR) 2}Ph2]2 and Fe(eta5-C 5H4[P{NP(S)(OR)2}R?2]) 2, respectively. The reactions of these ligands with AgSbF 6 in a 1: 1 molar ratio have been investigated. The resulting silver(i) complexes, derived from the selective coordination of the PS units, have been characterized by IR, NMR and MS (FAB) spectroscopy and, in selected cases, by X-ray crystallography. Monomeric, dimeric and polymeric solid-state structures, depending on the nature of the ligand backbone, have been found. The Royal Society of Chemistry 2007.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: chiral-phosphine-ligands. In my other articles, you can also check out more blogs about 12150-46-8
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate