1608-26-0, Name is Tris(dimethylamino)phosphine
, molecular formula is P[N(CH3)2]3, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 1608-26-0, Safety of Tris(dimethylamino)phosphine
Use of HMPT as solvent in photochemistry allows efficient photoreductions.Alkyl esters and especially non absorbing alkyl acetates are photoreduced in excellent yields into alkanes.In the latter case, a protonating agent is necessary.Numerous examples illustrate the generality and convenience of the reaction.This photoreduction involves an electron transfer from HMPT to ester.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of Tris(dimethylamino)phosphine
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate