Synthetic Route of 13440-07-8. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 13440-07-8, Name is Di(naphthalen-1-yl)phosphine oxide. In a document type is Article, introducing its new discovery.
We report a Pd-catalyzed intermolecular hydrophosphinylation of 1,3-dienes to afford chiral allylic phosphine oxides. Commodity dienes and air stable phosphine oxides couple to generate organophosphorus building blocks with high enantio- and regiocontrol. This method constitutes the first asymmetric hydrophosphinylation of dienes.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate