Synthetic Route of 224311-51-7, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.224311-51-7, Name is 2-(Di-tert-Butylphosphino)biphenyl, molecular formula is C20H27P. In a patent, introducing its new discovery.
A series of rhodium complexes of the form [Rh(L)2NBD]BF 4 where L represents a phosphine ligand and [Rh(L-L)NBD]BF 4 where (L-L) represents a diphosphine ligand and NBD = norbornadiene have been prepared. The complexes have been incorporated into Nafion by ion-exchange and the supported catalysts thus obtained have been compared with their homogeneous precursors for their activity as catalysts for the hydroformylation of hex-1-ene. The overall yield and the ratio of normal heptanal to branched products are reduced in all cases by introduction of the catalyst into Nafion. The modification of Nafion to produce a polymeric phosphine and its use as a ligand for hydroformylation using rhodium is also described.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate