A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1608-26-0, Name is Tris(dimethylamino)phosphine
, molecular formula is P[N(CH3)2]3. In a Article,once mentioned of 1608-26-0, Quality Control of: Tris(dimethylamino)phosphine
A new reagent is described for the determination of enantiomeric excess of chiral alcohols.This derivatizing agent allows an accurate analysis by 31P NMR.A large array of primary, secondary, and tertiary alcohols, functionalized or not, were successfully tested.Reagent 7 is easy to prepare and reacts alone with the chiral alcohol, at room temperature, eventually directly in the NMR tube.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: Tris(dimethylamino)phosphine
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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate