Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, Recommanded Product: 12150-46-8.
A series of homoleptic and heteroleptic platinum(ii) complexes [Pt(C?CFc)2(L-L)] (L-L = COD 1, 1,1?- bis(diphenylphosphino)ferrocene (dppf) 2), Q2[cis/trans-Pt(C 6F5)2(C?] (cis, Q = PMePh3, 3; trans, Q = NBu4, 4), (NBu4)[Pt(bzq)(C?CFc) 2] 5 (Hbzq = 7,8-benzoquinoline) and (NBu4) 2[Pt(C?CFc)4] 6 has been synthesized and characterized spectroscopically and the structures of 1?2CHCl3, 2 and 6?2H2O?2CH2Cl2 confirmed by single-crystal X-ray studies. The anion of complex 6, shows strong O-Hpi(C?C) interactions and weaker C-Clpi(C?C) contacts between the protons of two water and two CH2Cl2 molecules and the CalphaCbeta of mutually cis alkynyl groups. In this complex the presence of additional O-HH-C(Cp) and C-ClH-C(Cp) contacts gives rise to an extended bidimensional network. The optical and electrochemical properties of all derivatives have been examined. It is remarkable that for complexes 2 and 5 a facile oxidatively induced coupling, giving rise to 1,4-diferrocenylbutadiyne, is observed, this also having been proven by chemical oxidation.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of 1,1-Bis(diphenylphosphino)ferrocene. In my other articles, you can also check out more blogs about 12150-46-8
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate