50777-76-9, Name is 2-(Diphenylphosphino)benzaldehyde, molecular formula is C19H15OP, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 50777-76-9, Computed Properties of C19H15OP
Three palladium(II) complexes Pd(L)X (X = CH3CO2, Cl, I) of the conjugate base of 2-(diphenylphosphino)benzaldehyde benzoylhydrazone (HL) have been synthesized and characterized.Pd(L)(CH3CO2) is active in the catalytic hydrogenation of styrene, phenylacetylene and 1-octyne.While styrene is hydrogenated to ethylbenzene, alkynes are mainly hydrogenated to the corresponding olefins.Stable alkynylpalladium(II) complexes which are responsible for the loss of catalytic activity have been isolated and characterized.The X-ray structure of one of them, Pd(L)(CC-C6H5), has been determined together with that of the Pd(L)Cl complex.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C19H15OP. In my other articles, you can also check out more blogs about 50777-76-9
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate