Synthetic Route of 1079-66-9, An article , which mentions 1079-66-9, molecular formula is C12H10ClP. The compound – Chlorodiphenylphosphine played an important role in people’s production and life.
An expedient organic photoredox Pschorr reaction has been developed that opens up a synthetic route to 6 H-benzo[ c[chromenes. The process can be performed under mild conditions by using eosin Y as a photoredox catalyst and acetonitrile as the solvent. The diazonium salts can be either preformed or generated in situ from the corresponding amines with t-BuONO. The process is amenable to gram-sale synthesis of 6 H-benzo[ c[chromenes, which can be further transformed into both 6 H-benzo[ c[chromen-6-ones through oxidation or to 6 H-benzo[ c[chromen-6-amine through sp 3 C-H bond amination. The protocol provides an attractive route for the synthesis of a library of 6 H-benzo[ c[chromes.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate