In an article, published in an article, once mentioned the application of 17261-28-8, Name is 2-(Diphenylphosphino)benzoic acid,molecular formula is C19H15O2P, is a conventional compound. this article was the specific content is as follows.Recommanded Product: 17261-28-8
Water soluble sodium salts of (COD)RhCl(PAr3), where PAr3 is Ph2P(C6H4-2-COOH), Ph2P(C6H4-3-COOH), Ph2P(C6H4-4-COOH), PhP(C6H4-3-COOH)2, or P(C6H4-3-COOH)3, catalyze under phase transfer conditions the isomerization of 1-octen-3-ol to 3-octanone. The reaction rate depends on the position and number of the carboxyl groups in the phosphine ligand. (COD)RhCl[Ph2P(C6H4-2-C6H4-COOH], which exists as an equilibrium mixture with (COD)(H)RhCl(-OCOC6H4-2-PPh2) more reactive than the hydride-free catalysts. A hydride addition-elimination mechanism is suggested as the major pathway for the catalytic process.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate