Final Thoughts on Chemistry for 13991-08-7

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Related Products of 13991-08-7. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 13991-08-7, Name is 1,2-Bis(diphenylphosphino)benzene

Triplet-state ketones readily sensitized the photoreduction of bis(acetylacetonato)cobalt(II) or Cosolv2+ under atmospheric pressure of carbon monoxide to give Co(CO)4-.The low-valent cobalt could be trapped and isolated as phosphine-substituted metal carbonyl complexes.The crystal structure of one of the products, 2)2>PF6 has been determined.It is orthorhombic, space group Pbca, Z=8, with unit cell dimensions a 19.704(5), b 24.850(13), c 21.865(9) Angstroem.Phosphine-substituted iron(0) carbonyl complexes have also been isolated from similar photoreductions of iron(II) species.

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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate