Application of 1608-26-0. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1608-26-0, Name is Tris(dimethylamino)phosphine
Phosphorous triamides react with aliphatic diols and dibasic phenols: 1,6-hexanediol, 2,2?-(4-hydroxyphenyl)propane, 1,4-hydroquinone, and 4,4?-dihydroxybiphenyl in the temperature range 80-110C in diethylene glycol dimethyl ether or without a solvent to afford phosphorus-containing regular high-molecular products having an O 2P(NR2) moiety in the monomeric unit. The resulting poly(phosphoramidites) are capable of swelling in organic solvents, and they can be used as macroligands in the catalytic hydrogenation of styrene over rhodium(I) complexes.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate