Application of 12150-46-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene
A series of diiron dithiolate complexes bearing phosphine or isocyanide ligands, as the active site models of [FeFe]H2ases, has been prepared by carbonyl substitution and structurally characterized. While complexes [(mu-EDT)Fe2(CO)5L1] (EDT = SCH 2CH2S, L1 = PPh3, 3; Ph 2PCH2PPh2, 4; tBuNC, 5) were prepared by reactions of (mu-EDT)Fe2(CO)6 (1) with PPh3, Ph2PCH2PPh2 (dppm), or tBuNC in the presence of Me3NO·2H2O in MeCN in 52-82% yields, complex (mu-EDT)Fe2(CO)4( tBuNC)2 (6) was produced by reaction of 1 with 2 equivalents of tBuNC in CH2Cl2 in 42% yield. Treatment of 1 or (mu-PDT)Fe2(CO)6 (PDT = SCH 2CH2CH2S) (2) with Me3NO· 2H2O followed by addition of 4-PyN(PPh2)2 (Py = C5H4N) gave unexpected products (mu-EDT)Fe 2(CO)5[Ph2PP(O)Ph2] (7), (mu-EDT)Fe2(CO)5(Ph2PNHPy-4) (8), (mu-PDT)Fe2(CO)5[Ph2PP(O)Ph2] (9), and (mu-PDT)Fe2(CO)5(Ph2PNHPy-4) (10) in 20-38% yields, respectively. In addition, the asymmetrically disubstituted complex (mu-EDT)Fe2(CO)4(Ph2PCH 2CH2PPh2) (11) was obtained by reaction of 1 with Ph2PCH2CH2PPh2 (dppe) in refluxing xylene in 31% yield, whereas reaction of 2 with 1,1?- bis(diphenylphosphino)ferrocene (dppf) in refluxing xylene afforded the symmetrically disubstituted complex (mu-PDT)Fe2(CO) 4[(eta5-Ph2PC5H4) 2Fe] (12) in 28% yield. The complexes 3-9, 11, and 12 were characterized by elemental analysis, IR, and NMR spectroscopy, as well as for 3-7, 9, 11, and 12 by X-ray crystallography.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate