13991-08-7, Name is 1,2-Bis(diphenylphosphino)benzene, molecular formula is C30H24P2, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 13991-08-7, Safety of 1,2-Bis(diphenylphosphino)benzene
A highly enantioselective cobalt-catalyzed reverse prenylation of beta-ketoester with tertiary allylic carbonate to construct vicinal all-carbon quaternary carbon centers has been developed. By using the cobalt/(S,S)Ph-BPE complex generated in situ with zinc reduction, excellent branched to linear selectivity (>20:1) and up to 92% ee have been obtained.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of 1,2-Bis(diphenylphosphino)benzene. In my other articles, you can also check out more blogs about 13991-08-7
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate