Application of 224311-51-7, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 224311-51-7, C20H27P. A document type is Review, introducing its new discovery.
A series of achiral and chiral diene and the related ligands in transition-metal complexes is evaluated by percent buried volume (%Vbur) based on their molecular structures by X-ray analysis. Steric bulk of cyclic diene ligands in [Ru(acac)2L] and [RhClL]2 are sorted in the order of %Vbur. Recent developments on transition-metal catalyses using these ligands such as (i) conjugate arylations, alkenylation, and alkynylation, (ii) imine-arylations and alkenylations, (iii) kinetic resolutions, (iv) allylation, (v) cyclizations, (vi) defluorinations, (vii) C[sbnd]H bond activations, and (viii) cross-dimerizations are reviewed.
If you are hungry for even more, make sure to check my other article about 224311-51-7. Application of 224311-51-7
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate