Final Thoughts on Chemistry for Tri-p-tolylphosphine

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1038-95-5, Name is Tri-p-tolylphosphine, molecular formula is C21H21P. In a Article,once mentioned of 1038-95-5, Recommanded Product: 1038-95-5

The reaction of square-planar rhodium(I) complexes of the general formula P(4-tolyl)//3)//2RhClB with H//2 has been investigated where B is P(4-tolyl)//3, pyridine, or tetrahydrothiophene. NMR studies confirm that in all cases the product geometry has the two hydrogens cis to each other and the two phosphines trans to each other. The rate of dissociation of pyridene from the hydride is reported and compared with that of phosphine dissociation. Thermodynamic data for activation of H//2 by the phosphine and tetrahydrothiophene adducts are reported. From this information metal-hydrogen bond strengths can be calculated and the influence of B on this quantity determined.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate