In an article, published in an article, once mentioned the application of 224311-51-7, Name is 2-(Di-tert-Butylphosphino)biphenyl,molecular formula is C20H27P, is a conventional compound. this article was the specific content is as follows.category: chiral-phosphine-ligands
Herein, we report the development of a palladium-catalyzed chemoselective cross-coupling of (diborylmethyl)silanes with alkenyl bromides. The reaction shows broad scope with respect to alkenyl bromides and (diborylmethyl)silanes, affording a range of alpha-silyl-substituted allylic boronate esters in good-to-excellent yields. The practicality of the developed coupling reaction is demonstrated by the gram-scale synthesis of alpha-silyl-substituted allylic boronate ester.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate